Pickling — a Complex Subject Concisely Presented Pickling is one of the most basic pre-treatment steps in the processing of high-value metal manufacture, especially for ferrous materials. Pickling removes surface coatings or deposits from upstream manufacturing stages or oxide layers formed by chemical reaction with the air especially after extended storage periods. It thus creates a clean metallic surface prior to coating or for joining procedures such as welding. For steels, hydrochloric or sulphuric acids are usually employed, with their concentrations and bath temperatures optimised for the specific task in question. Special care must be taken especially with high tensile steels, to avoid hydrogen embrittlement. Spent pickling solutions can often be economically regenerated or used for other purposes if the concentration of dissolved metals is controlled.
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